Interfaces between proton-conducting ionic liquids and catalytic electrodes
The behavior of ionic liquids differs fundamentally from that of conventional aqueous electrolytes since they consist solely of charged molecular ions. This is particularly true for the electrochemical double layer at the interface to a polarized electrode. A compact structure of alternating anion and cation layers is formed, which also influences reactions crucial for fuel cell operation (e.g. oxygen reduction). We investigate this interfacial structure and its dependence on residual water content using atomic force microscopy as well as infrared and Raman spectroscopy.